From mononuclear iron phthalocyanines in catalysis to μ-nitrido diiron complexes and beyond
Sign Up to like & getrecommendations! Published in 2021 at "Catalysis Today"
DOI: 10.1016/j.cattod.2021.03.016
Abstract: Abstract For a long time biomimetic oxidation catalysis was mainly associated with metal porphyrin complexes. Phthalocyanine complexes, also belonging to large family of macrocyclic complexes have been under-investigated as catalysts until recently. In this review,… read more here.
Keywords: nitrido diiron; catalysis; iron phthalocyanines; chemistry ... See more keywords
Effect of acidity of oxide support on the activity and stability of μ-nitrido diiron phthalocyanine complex
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Engineering Research and Design"
DOI: 10.1016/j.cherd.2019.02.023
Abstract: Abstract Various oxides, including Al2O3, Fe2O3, SiO2, and ZrO2, were employed as catalyst supports for the oxidation of cyclohexane by a μ-nitrido-bis[tetra(tert-butyl)phthalocyaninatoiron] complex. These oxide supports were characterized by Brunauer–Emmett–Teller surface area measurements and NH3… read more here.
Keywords: nitrido diiron; diiron phthalocyanine; activity; acidity ... See more keywords
Cooperative behavior of perfluoro carboxylic acid on cyclohexane oxidation catalyzed by μ-nitrido diiron phthalocyanine complex
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Industrial and Engineering Chemistry"
DOI: 10.1016/j.jiec.2017.05.008
Abstract: Abstract μ-Nitrido diiron phthalocyanine complex has shown great performance in cyclohexane oxidation. Catalytic activity of μ-nitrido-bis[tetra(tert-butyl)phthalocyaninatoiron] complex could dramatically be enhanced in the presence of perfluoro carboxylic acid. Turnover number of cyclohexane oxidation reached 504,… read more here.
Keywords: nitrido diiron; perfluoro carboxylic; cyclohexane oxidation; carboxylic acid ... See more keywords