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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c00675
Abstract: Nitriles are widely used vibrational probes; however, the interpretation of their IR frequencies is complicated by hydrogen bonding (H-bonding) in protic environments. We report a new vibrational Stark effect (VSE) that correlates the electric field…
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Keywords:
nitrile infrared;
bonding protic;
hydrogen bonding;
infrared intensities ... See more keywords