High Nitrile Yields of Aerobic Ammoxidation of Alcohols Achieved by Generating •O2- and Br• Radicals over Iron-Modified TiO2 Photocatalysts.
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DOI: 10.1021/jacs.2c07061
Abstract: Catalytic ammoxidation of alcohols into nitriles is an essential reaction in organic synthesis. While highly desirable, conducting the synthesis at room temperature is challenging, using NH3 as the nitrogen source, O2 as the oxidant, and… read more here.
Keywords: yields aerobic; high nitrile; nitrile yields; ammoxidation alcohols ... See more keywords