Azo Compounds Derived from Electrochemical Reduction of Nitro Compounds for High Performance Li-Ion Batteries.
Sign Up to like & getrecommendations! Published in 2018 at "Advanced materials"
DOI: 10.1002/adma.201706498
Abstract: Organic compounds are desirable alternatives for sustainable lithium-ion battery electrodes. However, the electrochemical properties of state-of-the-art organic electrodes are still worse than commercial inorganic counterparts. Here, a new chemistry is reported based on the electrochemical… read more here.
Keywords: azo compounds; compounds high; ion; performance ... See more keywords
Direct Access to Amides from Nitro-Compounds via Aminocarbonylation and Amidation Reactions: A Minireview.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical record"
DOI: 10.1002/tcr.202100224
Abstract: The ubiquity of the amide bond in functional molecules including proteins, natural products, pharmaceuticals, agrochemicals and materials provides impetus to design and develop newer strategies for the generation of this linkage. Owing to growing awareness… read more here.
Keywords: aminocarbonylation amidation; nitro compounds; via aminocarbonylation; amidation reactions ... See more keywords
ZIF-67 derived CoSx/NC catalysts for selective reduction of nitro compounds
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Central South University"
DOI: 10.1007/s11771-021-4696-8
Abstract: Transition metal sulfides (TMSs)-based materials have been extensively investigated as effective non-noble catalysts for various applications. However, the exploration of TMSs-based catalysts for hydrogenation of nitro compounds is limited. Herein, CoSx/NC catalysts were prepared by… read more here.
Keywords: zif derived; nitro compounds; reduction nitro; cosx catalysts ... See more keywords
The reduction of organic nitro compounds by carbon monoxide as an effective strategy for the synthesis of N-heterocyclic compounds: a personal account
Sign Up to like & getrecommendations! Published in 2017 at "Rendiconti Lincei"
DOI: 10.1007/s12210-017-0601-7
Abstract: Reduction of suitably substituted organic nitro compounds by CO, catalyzed by different metal complexes, affords a variety of N-heterocyclic compounds. Carbon dioxide is the only stoichiometric byproduct. Several inter-molecular condensations have also been developed during… read more here.
Keywords: organic nitro; reduction; heterocyclic compounds; compounds carbon ... See more keywords
Visible-Light-Driven Porphyrin-Based Bimetallic Metal-Organic Frameworks for Selective Photoreduction of Nitro Compounds under Mild Conditions.
Sign Up to like & getrecommendations! Published in 2023 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c22686
Abstract: Selective reduction of nitroaromatics to the corresponding amines generally requires complex conditions, involving pressurized hydrogen, higher temperatures, or organic acids. In this work, we successfully prepared a series of porphyrin-based MOF photocatalysts (Pd-PMOFs, In-PMOFs, and… read more here.
Keywords: nitro compounds; compounds mild; hydrogen; porphyrin based ... See more keywords
Organocatalytic Reduction of Aromatic Nitro Compounds: The Use of Solid-Supported Phenyl(2-quinolyl)methanol
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c04196
Abstract: The reduction of aromatic nitro compounds has been performed employing a catalytic amount of Wang resin-supported phenyl(2-quinolyl)methanol (Wang-PQM) in the presence of an excess of NaBH4 to regenerate the reactive reducing species at the end… read more here.
Keywords: supported phenyl; nitro compounds; phenyl quinolyl; reduction ... See more keywords
Surfactant-Assisted Selective Oxidation of Aromatic Amines to Nitro Compounds by in Situ-Formed Performic Acid
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DOI: 10.1021/acsomega.9b00543
Abstract: Development of novel and greener methods for the selective oxidation of various organic compounds is a challenging task. Herein, a novel protocol for the selective oxidation of aromatic amines to nitroaromatics at room temperature is… read more here.
Keywords: performic acid; oxidation; oxidation aromatic; selective oxidation ... See more keywords
Organocatalytic oxidation of substituted anilines to azoxybenzenes and nitro compounds: mechanistic studies excluding the involvement of a dioxirane intermediate
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DOI: 10.1039/c6gc03174a
Abstract: An organocatalytic and environmentally friendly approach for the selective oxidation of substituted anilines was developed. Utilizing a 2,2,2-trifluoroacetophenone-mediated oxidation process, substituted anilines can be transformed into azoxybenzenes, while a simple treatment with MeCN and H2O2… read more here.
Keywords: substituted anilines; oxidation; excluding involvement; oxidation substituted ... See more keywords
One-pot synthesis of N-substituted pyrroles from nitro compounds and 2,5-hexadione over a heterogeneous cobalt catalyst
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DOI: 10.1039/c7nj01898c
Abstract: In this study, the one-pot heterocyclization of nitro compounds with 2,5-hexadione was studied for the synthesis of N-substituted pyrroles via a Paal–Knorr condensation process. The heterogeneous cobalt–nitrogen catalyst (Co–Nx/C-800-AT) was found to be active for… read more here.
Keywords: substituted pyrroles; synthesis substituted; one pot; nitro compounds ... See more keywords
Tandem imine formation via auto-hydrogen transfer from alcohols to nitro compounds catalyzed by a nanomagnetically recyclable copper catalyst under solvent-free conditions
Sign Up to like & getrecommendations! Published in 2021 at "RSC Advances"
DOI: 10.1039/d1ra02347k
Abstract: A direct imination reaction was developed by tandem reaction of alcohols and nitro compounds in the presence of Cu-isatin Schiff base-γ-Fe2O3 as a nanomagnetically recyclable catalyst under solvent-free conditions. By this method, various imines were… read more here.
Keywords: catalyst solvent; nanomagnetically recyclable; alcohols nitro; reaction ... See more keywords
Interaction of [В10H10]2– and [В12H12]2– with nitro compounds
Sign Up to like & getrecommendations! Published in 2017 at "Doklady Chemistry"
DOI: 10.1134/s0012500817110088
Abstract: The interaction of the [B10H10]2– and [B12H12]2– anions with aliphatic and aromatic nitro compounds (RNO2, where R = Et, n-Pr, i-Pr, tert-Bu, Ph) has been studied under irradiation with visible and UV light. It has… read more here.
Keywords: nitro compounds; interaction 10h10; 10h10 12h12; 12h12 nitro ... See more keywords