Articles with "nitro group" as a keyword



Hemicyanine‐Based Highly Water‐Soluble Probe for Extracellular Nitroreductase

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Published in 2024 at "ChemBioChem"

DOI: 10.1002/cbic.202400257

Abstract: Nitroreductase (NTR) has long been a target of interest for its important role involved in the nitro compounds metabolism. Various probes have been reported for NTR analysis, but rarely able to distinguish the extracellular NTR… read more here.

Keywords: hemicyanine; nitro group; group; probe extracellular ... See more keywords
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High Turnover Pd/C Catalyst for Nitro Group Reductions in Water. One-Pot Sequences and Syntheses of Pharmaceutical Intermediates.

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Published in 2021 at "Organic letters"

DOI: 10.1021/acs.orglett.1c03258

Abstract: Commercially available Pd/C can be used as a catalyst for nitro group reductions with only 0.4 mol % Pd loading. The reaction can be performed using either silane as a transfer hydrogenating agent or simply… read more here.

Keywords: nitro group; high turnover; group reductions; catalyst nitro ... See more keywords

How does the combination of the nitro group and fluorine atoms affect the (co)crystallization behaviour of arylenediamines?

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Published in 2023 at "CrystEngComm"

DOI: 10.1039/d3ce00327b

Abstract: A series of phenylenediamines containing the NO2 group and 3 to 0 fluorine atoms and 18-crown-6 ether were used to study the dependence of the stoichiometry and supramolecular structure of... read more here.

Keywords: fluorine atoms; combination nitro; group fluorine; nitro group ... See more keywords

Tuning sensing efficacy of anthraimidazoledione-based charge transfer dyes: nitro group positioning impact.

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Published in 2024 at "Dalton transactions"

DOI: 10.1039/d3dt04172g

Abstract: Anthraimidazoledione-based optical sensors have been designed by varying the position of the nitro functional group. All three positional isomers showed highly colored, photostable optical signals owing to intramolecular charge transfer interactions. Despite having the same… read more here.

Keywords: charge transfer; anthraimidazoledione based; group; nitro group ... See more keywords

Efficient Buchwald–Hartwig and nitrene-mediated five-membered ring closure approaches to the total synthesis of quindoline. Unexpected direct conversion of a nitro group into a phosphazene

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Published in 2023 at "RSC Advances"

DOI: 10.1039/d3ra02468g

Abstract: Two total syntheses of quindoline, which take place through the intermediacy of 3-nitroquinoline derivatives, are reported. The general synthetic sequence involves construction of the latter by mechanochemical condensation of benzaldehydes with 2-amino-nitrostyrene, followed either by… read more here.

Keywords: quindoline unexpected; nitrene mediated; buchwald hartwig; nitro group ... See more keywords

Shining light on the nitro group: distinct reactivity and selectivity.

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Published in 2024 at "Chemical communications"

DOI: 10.1039/d4cc02582b

Abstract: The nitro moiety is an indispensable functional group in organic synthesis due to its facile introduction and reduction to the corresponding amines for a plethora of organic transformations. Owing to its distinct electronegative and conventional… read more here.

Keywords: group distinct; light nitro; nitro group; group ... See more keywords

Conversion of 1-alkylated 5(6)-nitro-1H-benzimidazoles into Radical Anions and Characterization of their Bioreductive Potential

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Published in 2025 at "Journal of The Electrochemical Society"

DOI: 10.1149/1945-7111/ade1fc

Abstract: Coupling the electron-rich benzimidazole system with a nitro group could provide a suitable scaffold for the development of drugs exerting selective cytotoxicity through hypoxia-activation or enzymatic activation of the nitro group. The bioreductive potential of… read more here.

Keywords: radical anions; alkylated nitro; nitro group; nitro benzimidazoles ... See more keywords

Structural Organization of Dibromodiazadienes in the Crystal and Identification of Br···O Halogen Bonding Involving the Nitro Group

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Published in 2022 at "Molecules"

DOI: 10.3390/molecules27165110

Abstract: Nitro functionalized dibromodiazadiene dyes were prepared and fully characterized including X-ray single crystal analysis. Electron deficient dibromodiazadienes were found to be able to act as donors of halogen bonding (XB), while the nitro group acted… read more here.

Keywords: nitro group; group; halogen bonding; structural organization ... See more keywords

Remote Detection and Visualization of Surface Traces of Nitro-Group-Containing Explosives

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Published in 2024 at "Photonics"

DOI: 10.3390/photonics11111065

Abstract: This paper presents the results of an experimental study of the possibility of remote visualization of traces of some nitro-group-containing explosives (TNT, RDX, HMX, Composition-B, and Tetryl) on the surface of aluminum foil using the… read more here.

Keywords: detection; containing explosives; nitro group; group containing ... See more keywords