Mechanism and Origin of Remote Stereocontrol in the Organocatalytic Enantioselective Formal C(sp2)-H Alkylation Using Nitroalkanes as Alkylating Agents.
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DOI: 10.1021/jacs.2c02941
Abstract: Experimental 13C kinetic isotope effects (KIEs) and density functional theory (DFT) calculations are used to evaluate the mechanism and origin of enantioselectivity in the formal C(sp2)-H alkylative desymmetrization of cyclopentene-1,3-diones using nitroalkanes as the alkylating… read more here.
Keywords: mechanism origin; nitroalkanes alkylating; formal sp2; using nitroalkanes ... See more keywords