Green synthesis of low-carbon chain nitroalkanes via a novel tandem reaction of ketones catalyzed by TS-1
Sign Up to like & getrecommendations! Published in 2018 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2018.01.022
Abstract: Abstract A green and efficient one-pot method has been developed for the synthesis of low-carbon chain nitroalkanes via a novel TS-1 catalyzed tandem oxidation of ketones with H2O2 and NH3. The tandem reaction including ammoxidation,… read more here.
Keywords: chain nitroalkanes; nitroalkanes via; low carbon; synthesis low ... See more keywords
Asymmetric C-Alkylation of Nitroalkanes via Enzymatic Photoredox Catalysis.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12197
Abstract: Tertiary nitroalkanes and the corresponding α-tertiary amines represent important motifs in bioactive molecules and natural products. The C-alkylation of secondary nitroalkanes with electrophiles is a straightforward strategy for constructing tertiary nitroalkanes; however, controlling the stereoselectivity… read more here.
Keywords: asymmetric alkylation; alkylation nitroalkanes; alkylation; nitroalkanes via ... See more keywords