Polymer supported Nickel nanoparticles as recyclable catalyst for the reduction of nitroarenes to anilines in aqueous medium
Sign Up to like & getrecommendations! Published in 2018 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2017.12.015
Abstract: Abstract Polymer supported nickel nanoparticles, generated by calcination under nitrogen of a Ni(II) containing polyacrylamide, catalyzed the hydrogenation of nitroarenes to anilines in aqueous medium at room temperature in the presence of NaBH4. The protocol… read more here.
Keywords: supported nickel; anilines aqueous; nitroarenes anilines; polymer supported ... See more keywords
Designing a Polyoxometalate-Incorporated Metal-Organic Framework for Reduction of Nitroarenes to Anilines by Sequential Proton-Coupled Electron Transfers.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00106
Abstract: Developing new photocatalysts for reduction of nitroarenes to anilines under mild conditions is very significant. Herein, a new polyoxometalate-based metal-organic framework (POMOF), {[Co(H2O)]2[Co2(H2O)6(TPT)][Co(TPT)PW11O39]}·3H2O·TPT (namely, CoW-TPT, TPT = 2,4,6-tri(4-pyridyl)-1,3,5-triazine), was prepared by incorporating Co(II)-substituted Keggin-type anions… read more here.
Keywords: framework; tpt; electron; nitroarenes anilines ... See more keywords
Controllable synthesis of carbon encapsulated iron phosphide nanoparticles for the chemoselective hydrogenation of aromatic nitroarenes to anilines
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry frontiers"
DOI: 10.1039/c7qi00803a
Abstract: Selective hydrogenation of nitroarenes is an important chemical transformation to obtain functionalized anilines as key intermediates for pharmaceuticals and fine chemicals. Compared to the well-studied noble metal catalysts, heterogeneous catalysts based on low-cost transition metals… read more here.
Keywords: phosphide nanoparticles; hydrogenation aromatic; hydrogenation; nitroarenes anilines ... See more keywords