Nitrogen Vacancies on 2D Layered W2 N3 : A Stable and Efficient Active Site for Nitrogen Reduction Reaction.
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DOI: 10.1002/adma.201902709
Abstract: Electrochemical nitrogen reduction reaction (NRR) under ambient conditions provides an avenue to produce carbon-free hydrogen carriers. However, the selectivity and activity of NRR are still hindered by the sluggish reaction kinetics. Nitrogen Vacancies on transition… read more here.
Keywords: nitrogen; nitrogen reduction; nitrogen vacancies; reduction reaction ... See more keywords
Comprehensive Understanding of the Thriving Ambient Electrochemical Nitrogen Reduction Reaction.
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DOI: 10.1002/adma.202007650
Abstract: The electrochemical method of combining N2 and H2 O to produce ammonia (i.e., the electrochemical nitrogen reduction reaction [E-NRR]) continues to draw attention as it is both environmentally friendly and well suited for a progressively… read more here.
Keywords: reduction reaction; nitrogen reduction; electrochemical nitrogen;
Atomically Dispersed Zinc(I) Active Sites to Accelerate Nitrogen Reduction Kinetics for Ammonia Electrosynthesis.
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DOI: 10.1002/adma.202103548
Abstract: Electrocatalytic nitrogen reduction (NRR) to produce ammonia (NH3 ) at ambient conditions is a promising alternative for the Haber-Bosch process. However, developing highly active and stable NRR catalysts to replace precious metals remains challenging. Herein,… read more here.
Keywords: active sites; dispersed zinc; nitrogen reduction; atomically dispersed ... See more keywords
Atomic‐Scale Homogeneous RuCu Alloy Nanoparticles for Highly Efficient Electrocatalytic Nitrogen Reduction
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DOI: 10.1002/adma.202205270
Abstract: Ruthenium (Ru) is the most widely used metal as an electrocatalyst for nitrogen (N2) reduction reaction (NRR) because of the relatively high N2 adsorption strength for successive reaction. Recently, it has been well reported that… read more here.
Keywords: alloy nanoparticles; homogeneous alloy; nitrogen reduction; alloy ... See more keywords
Recent Advances in the Application of Structural‐Phase Engineering Strategies in Electrochemical Nitrogen Reduction Reaction
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DOI: 10.1002/admi.202001215
Abstract: Ammonia (NH3) exists as an important chemical raw material in the chemical industry and national economy of all countries in the world. The widely used Haber–Bosch ammonia synthesis process not only requires a large amount… read more here.
Keywords: reduction reaction; reaction; nitrogen reduction; electrochemical nitrogen ... See more keywords
Three‐Phase Electrolysis by Gold Nanoparticle on Hydrophobic Interface for Enhanced Electrochemical Nitrogen Reduction Reaction
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DOI: 10.1002/advs.202002630
Abstract: Abstract Electrochemical nitrogen reduction reaction (NRR) provides a facile and sustainable strategy to produce ammonia (NH3) at ambient conditions. However, the low NH3 yield and Faradaic efficiency (FE) are still the main challenges due to… read more here.
Keywords: nitrogen reduction; phase; electrochemical nitrogen; three phase ... See more keywords
Boosting Nitrogen Reduction Reaction via Electronic Coupling of Atomically Dispersed Bismuth with Titanium Nitride Nanorods
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DOI: 10.1002/advs.202104245
Abstract: Electrocatalytic nitrogen reduction reaction (NRR) is a promising alternative to the traditional Haber–Bosch process. However, the sluggish kinetics and competitive hydrogen evolution reaction result in poor NH3 yield and low Faradaic efficiency (FE). Herein, single… read more here.
Keywords: reduction reaction; nitride nanorods; reaction; nitrogen reduction ... See more keywords
Improving Electrocatalytic Nitrogen Reduction Selectivity and Yield by Suppressing Hydrogen Evolution Reaction via Electronic Metal–Support Interaction
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DOI: 10.1002/aenm.202203032
Abstract: The electrochemical nitrogen reduction reaction (NRR) has the potential to replace the Haber–Bosch process for ammonia synthesis under ambient conditions. However, the selectivity and yield of the NRR are impractical, owing to the preferential binding… read more here.
Keywords: reaction; selectivity yield; hydrogen; nitrogen reduction ... See more keywords
Transition Metal‐dinitrogen Complex Embedded Graphene for Nitrogen Reduction Reaction
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DOI: 10.1002/cctc.201900536
Abstract: Conversion of nitrogen to ammonia (NH3) is one of the most important issue in the modern chemical industry. Transition metals (TM) have the special unoccupied and occupied d orbitals to accept the electrons from and… read more here.
Keywords: nitrogen reduction; embedded graphene; reaction; reduction reaction ... See more keywords
Os1B11N12/C2N as an efficient electrocatalyst for nitrogen reduction reaction.
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DOI: 10.1002/cssc.202102648
Abstract: Ammonia is one of the most important fertilizer feedstock and chemical precursors besides a promising hydrogen carrier. However, the electrochemical reduction of nitrogen to ammonia is impeded by the low selectivity and high limiting potential… read more here.
Keywords: os1b11n12 c2n; reaction; nitrogen reduction; reduction reaction ... See more keywords
Modulating the Active Sites of Oxygen-Deficient TiO2 by Copper Loading for Enhanced Electrocatalytic Nitrogen Reduction to Ammonia.
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DOI: 10.1002/smll.202200996
Abstract: The electrocatalytic nitrogen reduction reaction (NRR) provides a sustainable route for NH3 synthesis. However, the process is plagued by the strong NN triple bond and high reaction barrier. Modification of catalyst surface to increase N2… read more here.
Keywords: oxygen deficient; electrocatalytic nitrogen; deficient tio2; nitrogen reduction ... See more keywords