Catalytic Asymmetric Cycloadditions of Silyl Nitronates Bearing α-Aryl Group.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b00558
Abstract: 1,3-Dipolar cycloadditions of 2-alkylacroleins or atropaldehyde with triisopropylsilyl nitronates bearing an α-aryl group produced 3-aryl-2-isoxazolines having a chiral quaternary center in up to 94% ee and up to 88% yield with the aid of Corey's… read more here.
Keywords: aryl group; nitronates bearing; bearing aryl; group ... See more keywords