A Nitrone Dipolar Cycloaddition Strategy toward an Enantioselective Synthesis of Massadine.
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DOI: 10.1021/acs.orglett.8b01464
Abstract: An enantioselective route to the C,D-bicycle of massadine is reported. Enantiopure intermediates were generated by a single stereoselective reduction using the Corey-Bakshi-Shibata reagent. This initial stereoinduction was translated into the five contiguous stereocenters of the… read more here.
Keywords: nitrone dipolar; massadine; cycloaddition strategy; dipolar cycloaddition ... See more keywords