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Published in 2019 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.5157
Abstract: The bis(arylimino)pyridines, 2-[CMeN{2,6-{(4-FC6H4)2CH}2-4-NO2}]-6-(CMeNAr)C5H3N (Ar = 2,6-Me2C6H3 L1, 2,6-Et2C6H3 L2, 2,6-i-Pr2C6H3 L3, 2,4,6-Me3C6H2 L4, 2,6-Et2-4-MeC6H2 L5), each containing one N'-2,6-bis{di(4-fluorophenyl)methyl}-4-nitrophenyl group, have been synthesized by two successive condensation reactions from 2,6-diacetylpyridine. Their subsequent treatment with anhydrous…
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Keywords:
methyl nitrophenyl;
fluorophenyl methyl;
bis;
bis fluorophenyl ... See more keywords
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Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c06994
Abstract: Regioselective cyclocondensation of 2,4-diacetyl-5-hydroxy-5-methyl-3-(3-nitrophenyl/4-nitrophenyl)cyclohexanones 1a,b with cyanothioacetamide afforded the corresponding 7-acetyl-4-cyano-1,6-dimethyl-6-hydroxy-8-(3- and -4-nitrophenyl)-5,6,7,8-tetrahydrosoquinoline-3(2H)-thiones 2a,b. Reaction of compounds 2a,b with ethyl iodide, 2-chloroacetamide (4a), or its N-aryl derivatives 4b–e in the presence of sodium acetate trihydrate…
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Keywords:
group;
activity;
nitrophenyl group;
antioxidant properties ... See more keywords