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Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.7b01124
Abstract: Nitrosocarbonyl intermediates, generated at room temperature by oxidation of nitrile oxides, undergo clean ene reactions with trisubstituted cycloalkenes. Nitrosocarbonyl benzene follows a Markovnikov orientation and abstracts preferentially the twix hydrogens over the lone ones. With…
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Keywords:
trisubstituted cycloalkenes;
ene reactions;
nitrosocarbonyl intermediates;
effect ... See more keywords