Articles with "nitrosyl complexes" as a keyword



Iron-sulfur [2Fe-2S] nitrosyl complexes as new trend in synthesis of donors of nitric oxide for anti-aging therapy

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Published in 2017 at "Free Radical Biology and Medicine"

DOI: 10.1016/j.freeradbiomed.2017.10.073

Abstract: Aging is associated with dysfunctions in vascular smooth muscle cells, neurotransmission, renal and immune systems, to name just a few, many of which stems from decline in reliability of the regulatory functions of nitric oxide… read more here.

Keywords: medicine; nitrosyl complexes; iron sulfur; nitrosyl ... See more keywords
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Blue-to-red light triggered nitric oxide release in cytotoxic/cytostatic ruthenium nitrosyl complexes bearing biomimetic ligands

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Published in 2021 at "Journal of Photochemistry and Photobiology A: Chemistry"

DOI: 10.1016/j.jphotochem.2021.113520

Abstract: Abstract The nitrosyl complexes trans(L,L)-[RuNO(L)2Cl3] (L = indazole (I) and imidazole (II)) were synthesized and comprehensively characterized including by single crystal X-ray diffraction. Both compounds exhibit light-induced NO release under blue or green light (445,… read more here.

Keywords: ruthenium; nitrosyl complexes; cytotoxic; light ... See more keywords

T-Shaped Palladium and Platinum {MNO}10 Nitrosyl Complexes

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Published in 2024 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.3c03434

Abstract: The synthesis and characterization of a homologous series of T-shaped {MNO}10 nitrosyl complexes of the form [M(PR3)2(NO)]+ (M = Pd, Pt; R = tBu, Ad) are reported. These diamagnetic nitrosyls are obtained from monovalent or… read more here.

Keywords: mno nitrosyl; shaped palladium; palladium platinum; nitrosyl complexes ... See more keywords

In Situ FT-IR Spectroelectrochemistry Reveals Mechanistic Insights into Nitric Oxide Release from Ruthenium(II) Nitrosyl Complexes

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Published in 2024 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.4c03185

Abstract: Ruthenium(II) tetraamine nitrosyl complexes with N-heterocyclic ligands are known for their potential as nitric oxide (NO•) donors, capable of releasing NO• through either direct photodissociation or one-electron reduction of the Ru(II)NO+ center. This study delivers… read more here.

Keywords: ruthenium; reduction; nitrosyl complexes; nitrosyl ... See more keywords

Photorelease of nitric oxide (NO) on ruthenium nitrosyl complexes with phenyl substituted terpyridines

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Published in 2017 at "New Journal of Chemistry"

DOI: 10.1039/c7nj00866j

Abstract: We investigated the influence of the nature of the substituent on the 4′-position of terpyridine ligands and the geometry around the metal ion on the photosensitization of ruthenium nitrosyl complexes. This was achieved by synthesizing… read more here.

Keywords: phtpy cl2; nitrosyl complexes; ruthenium nitrosyl;

Ruthenium-nitrosyl complexes as NO-releasing molecules, potential anticancer drugs, and photoswitches based on linkage isomerism.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt00290f

Abstract: The synthesis of new types of mono- and polynuclear ruthenium nitrosyl complexes is driving progress in the field of NO generation for a variety of applications. Light-induced Ru-NO bond dissociation in solution may involve transient… read more here.

Keywords: potential anticancer; nitrosyl complexes; ruthenium nitrosyl; anticancer drugs ... See more keywords

Photo-triggered NO release of nitrosyl complexes bearing first-row transition metals and therapeutic applications

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Published in 2024 at "Chemical Science"

DOI: 10.1039/d4sc06820c

Abstract: In biological systems, nitric oxide (NO) is a crucial signaling molecule that regulates a wide range of physiological and pathological processes. Given the significance of NO, there has been considerable interest in delivering NO exogenously,… read more here.

Keywords: transition; first row; nitrosyl complexes; row transition ... See more keywords

Effects of Laser Radiation on Mitochondria and Mitochondrial Proteins Subjected to Nitric Oxide

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Published in 2018 at "Frontiers in Medicine"

DOI: 10.3389/fmed.2018.00112

Abstract: The biological roles of heme and nonheme nitrosyl complexes in physiological and pathophysiological conditions as metabolic key players are considered in this study. Two main physiological functions of protein nitrosyl complexes are discussed—(1) a depot… read more here.

Keywords: nitrosyl complexes; protein nitrosyl; nitric oxide; activity ... See more keywords