Structure and Bonding of High‐Spin Nitrosyl–Iron(II) Compounds with Mixed N,O‐Chelators and Aqua Ligands
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DOI: 10.1002/ejic.201601329
Abstract: High-spin nitrosyl-iron centres of the Enemark-Feltham {FeNO}(7) type exist in aqueous solution. Examples include the tentative brown-ring species [Fe(H2O)(5)(NO)](2+) and a tentative Fe-II/edta/NO species formed in the processes for scrubbing NO from flue-gas streams. Inert-gas… read more here.
Keywords: high spin; nitrosyl iron; chemistry; h2o ... See more keywords
The Structural Chemistry of Stable High‐Spin Nitrosyl–Iron(II) Compounds with Aminecarboxylato Co‐Ligands in Aqueous Solution
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DOI: 10.1002/ejic.201601330
Abstract: Four crystalline nitrosyl-iron compounds of the {FeNO}(7)(S = 3/2) type with aminecarboxylato co-ligands were prepared from aqueous solutions of iron(II) sulfate, an equimolar amount of one of the co-ligands ethylenediamine-N,N'-diacetate (edda), nitrilotriacetate (nta), N,N'-bis(2-hydroxyethyl)ethylenediamine-N,N'-diacetate (bhedda)… read more here.
Keywords: aminecarboxylato ligands; nitrosyl iron; iron compounds; chemistry ... See more keywords
High-Spin Nitrosyl–Iron(II) Compounds
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DOI: 10.1002/ejic.201700383
Abstract: Invited for the cover of this issue is the group of Peter Klufers from Ludwig-Maximilians-Universitat Munchen, Germany. The cover image shows a laboratory-scale bubble column, which was used for the nitrosation of a dissolved ferrous… read more here.
Keywords: high spin; nitrosyl iron; iron compounds; chemistry ... See more keywords
Albumin as a prospective carrier of the nitrosyl iron complex with thiourea and thiosulfate ligands under aerobic conditions.
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DOI: 10.1039/d2dt00291d
Abstract: High-molecular-weight dinitrosyl iron complexes (DNICs) are formed in living systems and are a stable depot of nitrogen monoxide (NO). In this work, using experimental and theoretical methods, we investigated the interaction of their synthetic analog,… read more here.
Keywords: albumin prospective; carrier nitrosyl; prospective carrier; nitrosyl iron ... See more keywords
NO-Donor Nitrosyl Iron Complex with 2-Aminophenolyl Ligand Induces Apoptosis and Inhibits NF-κB Function in HeLa Cells.
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DOI: 10.3390/scipharm86040046
Abstract: NO donating iron nitrosyl complex with 2-aminothiophenyl ligand (2-AmPh complex) was studied for its ability to cause cell death and affect nuclear factor kappa B (NF-κB) signaling. The complex inhibited viability of HeLa cells and… read more here.
Keywords: donor nitrosyl; nitrosyl iron; iron complex; iron ... See more keywords