Can a Nitrosyl of a Mn(II)-Porphyrin Complex Release Nitroxyl/HNO?
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DOI: 10.1021/acs.inorgchem.1c02606
Abstract: In general, the nitrosyl complexes of Mn(II)-porphyrinate having the {Mn(NO)}6 configuration are not considered as HNO or nitroxyl (NO-) donors because of [MnI-NO+] nature. A nitrosyl complex of Mn(II)-porphyrin, [Mn(TMPP2-)(NO)], 1 [TMPPH2 = 5,10,15,20-tetrakis-4-methoxyphenylporphyrin], is… read more here.
Keywords: hno; porphyrin complex; complex release; nitrosyl porphyrin ... See more keywords