Articles with "nitroxide radical" as a keyword



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The study of nitroxide radical redox-couple and anatase surface interaction: a guide to choose the best sensitizer

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Published in 2019 at "Theoretical Chemistry Accounts"

DOI: 10.1007/s00214-019-2452-z

Abstract: Nitroxide radical redox-couple compounds have the potentials to be applied as a redox couple in dye-sensitized solar cell applications since their standard reduction potential reached almost 1 V. Unfortunately, many reports revealed the limitations of nitroxide… read more here.

Keywords: nitroxide radical; redox couple; radical redox; surface ... See more keywords
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Oral administration of the nitroxide radical TEMPOL exhibits immunomodulatory and therapeutic properties in multiple sclerosis models

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Published in 2017 at "Brain, Behavior, and Immunity"

DOI: 10.1016/j.bbi.2017.02.018

Abstract: Therapies with both immunomodulatory and neuroprotective properties are thought to have the greatest promise in reducing the severity and progression of multiple sclerosis (MS). Several reactive oxygen (ROS) and reactive nitrogen species (RNS) are implicated… read more here.

Keywords: tempol; disease; severity; multiple sclerosis ... See more keywords
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Nitroxide radical-containing nanoparticles attenuate tumorigenic potential of triple negative breast cancer.

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Published in 2018 at "Biomaterials"

DOI: 10.1016/j.biomaterials.2018.05.042

Abstract: The critical importance of reactive oxygen species (ROS) as oncogene activators and essential secondary messengers in cancer cell survival have been widely reported. Since oxidative stress has been implicated as being pivotal in various cancers,… read more here.

Keywords: negative breast; containing nanoparticles; radical containing; nitroxide radical ... See more keywords
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Redox chemistry of nitrogen-doped CNT-encapsulated nitroxide radical polymers for high energy density and rate-capability organic batteries

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Published in 2020 at "Chemical Engineering Journal"

DOI: 10.1016/j.cej.2020.127402

Abstract: Abstract To enhance the electrochemical performance and identify the redox reaction of a nitroxide radical-based organic battery, poly(2,2,6,6-tetramethylpiperidinyloxy-4-vinylmethacrylate) (PTMA) as nitroxide radical polymer is synthesized and used to fill the central pore of nitrogen-doped carbon… read more here.

Keywords: nitroxide radical; rate capability; nitrogen; chemistry ... See more keywords
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A family of 2p-3d complexes based on 4,5-dimethyltriazole nitronyl nitroxide radical: synthesis, structure, and magnetic properties

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Published in 2020 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2020.120122

Abstract: Abstract Three 2p-3d complexes were successfully synthesized by using 4,5-dimethyltriazole nitronyl nitroxide radical. All of the complexes with the same formula of [M(hfac)2(4,5-di-Me-3-NIT-trz)2] [M = Co(II) 1, Ni(II) 2, Cu(II) 3; 4,5-di-Me-3-NIT-trz = 2-[3-(4,5-dimethyl-l,2,4-triazolyl)]-4,4,5,5-tetramethylimida- zoline-1-oxyl-3-oxide;… read more here.

Keywords: nitronyl nitroxide; magnetic properties; dimethyltriazole nitronyl; nitroxide radical ... See more keywords
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Nitroxide radical-containing nanoparticles as potential candidates for overcoming drug resistance in epidermoid cancers

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Published in 2017 at "Polymer"

DOI: 10.1016/j.polymer.2017.02.052

Abstract: Abstract Multidrug resistance in cancer cells contributes to the failure of conventional chemotherapy in more than 90% of cancer patients (metastatic). This is attributed to reactive oxygen species (ROS)-regulated drug efflux proteins, P-glycoprotein (P-gp) and… read more here.

Keywords: drug resistance; containing nanoparticles; drug; radical containing ... See more keywords
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Nitroxide Radical Polymer–Solvent Interactions and Solubility Parameter Determination

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Published in 2020 at "Macromolecules"

DOI: 10.1021/acs.macromol.0c01739

Abstract: Redox-active polymers such as macromolecular nitroxide radicals have been studied as electrode materials for organic batteries and electronics. Polymer–solvent interactions are essential to process... read more here.

Keywords: interactions solubility; polymer solvent; solubility parameter; radical polymer ... See more keywords
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Conjugated Nitroxide Radical Polymers: Synthesis and Application in Flexible Energy Storage Devices.

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Published in 2019 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.8b21073

Abstract: The synthesis and electrochemical behavior of nitroxide radical conjugated polymers (NCPs) have long been an intriguing topic in redox polymer-based energy storage. However, common (electro)chemical oxidation polymerization methods have proved difficult in the synthesis of… read more here.

Keywords: storage; flexible energy; well defined; energy storage ... See more keywords
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Nitroxide radical-containing polynorbornenes by ring-opening metathesis polymerization as stabilizing agents for polyolefins

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Published in 2019 at "Polymer Chemistry"

DOI: 10.1039/c9py00769e

Abstract: A series of original 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-containing dicarboximide norbornene monomers have been synthesized and polymerized via ring-opening metathesis polymerization using the Grubbs 3rd generation catalyst. read more here.

Keywords: nitroxide radical; metathesis polymerization; ring opening; opening metathesis ... See more keywords
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Nitroxide radical polymers for emerging plastic energy storage and organic electronics: fundamentals, materials, and applications

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Published in 2021 at "Materials horizons"

DOI: 10.1039/d0mh01391a

Abstract: We review the electrochemical theory, material design, and device fabrication for nitroxide radical polymers in emerging plastic energy storage and organic electronics. read more here.

Keywords: emerging plastic; energy storage; radical polymers; nitroxide radical ... See more keywords
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A new nitronyl nitroxide radical with salicylic acid framework attenuates blood–brain barrier disruption and oxidative stress in a rat model of middle cerebral artery occlusion

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Published in 2022 at "Neuroreport"

DOI: 10.1097/wnr.0000000000001764

Abstract: Objectives A new nitronyl nitroxide radical with a salicylic acid framework (SANR) has been demonstrated to exert antioxidant effects in the previous study by our team. The current study has assessed the protective effect of… read more here.

Keywords: nitronyl nitroxide; salicylic acid; nitroxide radical; acid framework ... See more keywords