Chemoselective Oxidation of p-Methoxybenzyl Ethers by an Electronically Tuned Nitroxyl Radical Catalyst.
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DOI: 10.1021/acs.orglett.0c01839
Abstract: The oxidation of p-methoxy benzyl (PMB) ethers was achieved using nitroxyl radical catalyst 1, which contains electron-withdrawing ester groups adjacent to the nitroxyl group. The oxidative deprotection of the PMB moieties on the hydroxy groups… read more here.
Keywords: nitroxyl radical; oxidation methoxybenzyl; radical catalyst; chemoselective oxidation ... See more keywords
Slow magnetic relaxation and strong magnetic coupling in the nitroxyl radical complexes of lanthanide(iii) with diamagnetic ground state (Ln = Lu, Eu)
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DOI: 10.1039/d4sc05035e
Abstract: Radical lanthanide complexes are appealing platforms to investigate the possibility to engineer relevant magnetic couplings between the two magnetic centers by exploiting the strongly donating magnetic orbitals of the radical. In this paper, we report… read more here.
Keywords: slow magnetic; relaxation strong; magnetic relaxation; nitroxyl radical ... See more keywords
Evidence for efficient anchoring in nitroxyl radical thin films: an experimental XPS/NEXAFS and theoretical DFT/TD-DFT study
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DOI: 10.1039/d4tc00427b
Abstract: Nitroxide radicals’ adsorption mechanisms and film properties tunable by appropriately selecting the substrate. read more here.
Keywords: anchoring nitroxyl; radical thin; dft; efficient anchoring ... See more keywords