An evaluation of the impact of SG1 disproportionation and the addition of styrene in NMP of methyl methacrylate
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DOI: 10.1002/aic.16111
Abstract: A kinetic modeling study is presented for batch nitroxide mediated polymerization (NMP) of methyl methacrylate(MMA; nitroxide: N-tert-butyl-N-[1-diethylphosphono-(2,2-dimethylpropyl)] (SG1)). Arrhenius parameters for SG1 dis-proportionation (A 5 1.4 107Lmol21s21;Ea5 23 kJ mol21) are reported, based on homopolymerization… read more here.
Keywords: methyl methacrylate; nmp methyl; evaluation impact; styrene ... See more keywords