ETS‐NOCV Analysis of σ‐Donation and π‐Backdonation in Complexes of Boron Based Lewis Acids with N2, CO and NH3
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DOI: 10.1002/ejic.202400845
Abstract: Lewis acids B(SiR3)3 and B(GeR3)3 form anomalously strong complexes with Lewis bases N2 and CO. Intramolecular B‐N/C bonds are generally in the range 1.45‐1.50 Å and shorter than the sum of B and N/C covalent radii. Bonding analyses… read more here.
Keywords: backdonation; donation; lewis acids; ets nocv ... See more keywords
EDA‐NOCV analysis of carbene‐borylene bonded dinitrogen complexes for deeper bonding insight: A fair comparison with a metal‐dinitrogen system
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DOI: 10.1002/jcc.26832
Abstract: Binding of dinitrogen (N2) to a transition metal center (M) and followed by its activation under milder conditions is no longer impossible; rather, it is routinely studied in laboratories by transition metal complexes. In contrast,… read more here.
Keywords: nocv analysis; eda nocv; dinitrogen complexes; dinitrogen ... See more keywords