Tuning the Diradical Character of Pentacene Derivatives via Non-Benzenoid Coupling Motifs
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c02027
Abstract: The development of functional organic molecules requires structures of increasing size and complexity, which are typically obtained by the covalent coupling of smaller building blocks. Herein, with the aid of high-resolution scanning tunneling microscopy/spectroscopy and… read more here.
Keywords: tuning diradical; character; diradical character; character pentacene ... See more keywords
On-surface synthesis of non-benzenoid conjugated polymers by selective atomic rearrangement of ethynylarenes
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc04722e
Abstract: Here, we report a new on-surface synthetic strategy to precisely introduce five-membered units into conjugated polymers from specifically designed precursor molecules that give rise to low-bandgap fulvalene-bridged bisanthene polymers. The selective formation of non-benzenoid units… read more here.
Keywords: surface synthesis; synthesis non; conjugated polymers; polymers selective ... See more keywords