σ versus π‐radical: Tuning the electronic nature of neutral carbon (I) compounds with three non‐bonding electrons
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26964
Abstract: The bonding and reactivity of the hypo‐coordinated compounds with one, two, and four non‐bonding electrons namely, carbon‐centered free radical, carbenes, and carbones were well earlier established. Here, we report stability, bonding and reactivity of compounds… read more here.
Keywords: three non; carbon; non bonding; versus radical ... See more keywords
Evoking non-bonding S-π interaction by aryl phosphine sulfide for selectively enhanced electronic property of organic semiconductors
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2019.122562
Abstract: Abstract Selective tuning of optoelectronic properties of organic semiconductors is one of the most significant challenges in organoelectronics. Herein, on the basis of aryl phosphine sulfide (APS), we show that the electronic performance can be… read more here.
Keywords: non bonding; aryl phosphine; organic semiconductors; interaction ... See more keywords
Engineering oxygen nonbonding states in high entropy hydroxides for scalable water oxidation
Sign Up to like & getrecommendations! Published in 2025 at "Nature Communications"
DOI: 10.1038/s41467-025-61766-2
Abstract: The lattice oxygen oxidation mechanism typically requires the removal of electrons from the metal-oxygen band, which may cause structural instability due to a decrease in the metal-oxygen bond order. To address this challenge, we introduce… read more here.
Keywords: oxygen non; oxygen; entropy hydroxides; non bonding ... See more keywords
On the non-bonding valence band and the electronic properties of poly(triazine imide), a graphitic carbon nitride
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc00667k
Abstract: Graphitic carbon nitrides are covalently-bonded, layered, and crystalline semiconductors with high thermal and oxidative stability. These properties make graphitic carbon nitrides potentially useful in overcoming the limitations of 0D molecular... read more here.
Keywords: graphitic carbon; carbon; non bonding; bonding valence ... See more keywords