Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex
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DOI: 10.1038/ncomms14839
Abstract: Terminal cobalt(IV)–oxo (CoIV–O) species have been implicated as key intermediates in various cobalt-mediated oxidation reactions. Herein we report the photocatalytic generation of a mononuclear non-haem [(13-TMC)CoIV(O)]2+ (2) by irradiating [CoII(13-TMC)(CF3SO3)]+ (1) in the presence of… read more here.
Keywords: cobalt; cobalt oxo; reactivity; mononuclear non ... See more keywords