Ionic equilibrium in mixtures of polar protophobic and protophilic non-hydrogen bond donor solvents: Acids, salts, and indicators in acetonitrile with 4 mass % dimethylsulfoxide
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2020.114560
Abstract: Abstract Acetonitrile (AN) and dimethylsulfoxide (DMSO) belong to the so-called polar non-hydrogen bond donor solvents, in accordance with Bordwell's classification. At that, according to Kolthoff, AN is a protophobic, and DMSO is an expressed protophilic… read more here.
Keywords: donor solvents; hydrogen bond; non hydrogen; bond donor ... See more keywords
Acid dissociation constants in selected dipolar non-hydrogen-bond-donor solvents (IUPAC Technical Report)
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DOI: 10.1515/pac-2024-0276
Abstract: Abstract This compilation includes more than 9000 pK a values determined in seven dipolar non-hydrogen-bond-donor solvents {dimethyl sulfoxide, acetonitrile, N,N-dimethylformamide, pyridine, acetone, 4-methyl-1,3-dioxolan-2-one (propylene carbonate), oxolane (tetrahydrofuran)} for close to 5000 acids collected from around… read more here.
Keywords: dipolar non; hydrogen bond; bond donor; donor solvents ... See more keywords