Design and Synthesis of Kekulè and Non-Kekulè Diradicaloids via the Radical Periannulation Strategy: The Power of Seven Clar's Sextets.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c09637
Abstract: This work introduces an approach to uncoupling electrons via maximum utilization of localized aromatic units, i.e., the Clar's π-sextets. To illustrate the utility of this concept to the design of Kekulé diradicaloids, we have synthesized… read more here.
Keywords: system; clar sextets; non kekul; kekul non ... See more keywords
A Persistent Concealed Non-Kekulé Nanographene: Synthesis and in-situ Characterization
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DOI: 10.1039/d4qo02019g
Abstract: Concealed non-Kekulé (CNK) nanographenes have recently gained attention as promising non-Kekulé model systems due to their distinctive antiferromagnetic electronic spins, which offer potential applications in spintronics and quantum information science.... read more here.
Keywords: kekul nanographene; concealed non; synthesis situ; non kekul ... See more keywords