A General Strategy for Open‐Flask Alkene Isomerization by Ruthenium Hydride Complexes with Non‐Redox Metal Salts
Sign Up to like & getrecommendations! Published in 2017 at "ChemCatChem"
DOI: 10.1002/cctc.201700687
Abstract: A homogenous metal hydride (M−H) catalyst for isomerization normally requires rigorous air‐free techniques. Here, we demonstrate a highly efficient protocol in which simple non‐redox metal ions as Lewis acids can promote olefin isomerization dramatically with… read more here.
Keywords: non redox; hydride; redox metal; open flask ... See more keywords
Mechanisms of metal-dependent non-redox decarboxylases from quantum chemical calculations
Sign Up to like & getrecommendations! Published in 2021 at "Computational and Structural Biotechnology Journal"
DOI: 10.1016/j.csbj.2021.05.044
Abstract: Quantum chemical calculations are today an extremely valuable tool for studying enzymatic reaction mechanisms. In this mini-review, we summarize our recent work on several metal-dependent decarboxylases, where we used the so-called cluster approach to decipher… read more here.
Keywords: non redox; decarboxylase; quantum chemical; mechanisms metal ... See more keywords
Heat shock protein genes in the green alga Tetraselmis suecica and their role against redox and non-redox active metals.
Sign Up to like & getrecommendations! Published in 2019 at "European journal of protistology"
DOI: 10.1016/j.ejop.2019.01.006
Abstract: Microalgae are capable of tolerating variations in water temperature and sudden exposures to toxic substances, and cellular heat shock proteins (HSPs) help to protect cells from such stress. Here, we determined the complete open reading… read more here.
Keywords: non redox; heat shock; suecica; redox active ... See more keywords
Non-redox metal ions accelerated oxygen atom transfer by Mn-Me 3 tacn complex with H 2 O 2 as oxygen resource
Sign Up to like & getrecommendations! Published in 2018 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2018.01.022
Abstract: Abstract This work demonstrates a novel strategy that the introduction of non-redox metal ions as Lewis acids to the classic dinuclear manganese complex [MnIV2(μ-O)3(Me3tacn)2](PF6)2 can greatly promote the alkene epoxidation efficiency under mild conditions with… read more here.
Keywords: redox metal; oxygen; non redox; metal ions ... See more keywords
Selenite Sorption on Hydrated CEM-V/A Cement in the Presence of Steel Corrosion Products: Redox vs. Non-redox Sorption.
Sign Up to like & getrecommendations! Published in 2020 at "Environmental science & technology"
DOI: 10.1021/acs.est.9b06876
Abstract: Reinforced cementitious structures in nuclear waste repositories will act as barriers that limit the mobility of radionuclides (RNs) in case of eventual leakage. CEM-V/A cement, a ternary blended cement with blast furnace slag (BFS) and… read more here.
Keywords: steel corrosion; non redox; cement; sorption ... See more keywords