Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes
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DOI: 10.1021/acscentsci.6b00368
Abstract: Monosubstituted cycloalkanes undergo regio- and enantioselective aliphatic C–H oxidation with H2O2 catalyzed by biologically inspired manganese catalysts. The reaction furnishes the corresponding ketones resulting from oxidation at C3 and C4 methylenic sites (K3 and K4,… read more here.
Keywords: aliphatic bonds; oxidation nonactivated; enantioselective oxidation; oxidation ... See more keywords