Cobalt-Catalyzed Intermolecular Markovnikov Hydroamination of Nonactivated Olefins: N2-Selective Alkylation of Benzotriazole.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.9b04375
Abstract: Cobalt-catalyzed Markovnikov-selective hydroamination of nonactivated olefins was developed. Hydrogen atom transfer from a catalytically generated cobalt(III)-hydride complex to the olefins proceeded regioselectively, and the nucleophilic addition of benzotriazoles occurred selectively at their N2-positions. The synthetic… read more here.
Keywords: nonactivated olefins; catalyzed intermolecular; intermolecular markovnikov; cobalt catalyzed ... See more keywords
Plant-Based Nonactivated Olefins: A New Class of Renewable Monomers for Controlled Radical Polymerization
Sign Up to like & getrecommendations! Published in 2018 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b05926
Abstract: In light of fossil fuel depletion and a general necessity for sustainable development, the synthesis of polymers from renewable resources is gaining more and more importance, yet industrially relevant radical polymerizations still struggle with the… read more here.
Keywords: nonactivated olefins; based nonactivated; controlled radical; olefins new ... See more keywords