Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-Oxo Intermediate.
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DOI: 10.1021/jacs.7b11400
Abstract: The reaction of [(PyNMe3)FeII(CF3SO3)2], 1, with excess peracetic acid at -40 °C generates a highly reactive intermediate, 2b(PAA), that has the fastest rate to date for oxidizing cyclohexane by a nonheme iron species. It exhibits… read more here.
Keywords: meo pynme3; highly reactive; spectroscopic dft; fev ... See more keywords
Acid-induced nitrite reduction of nonheme iron(ii)-nitrite: mimicking biological Fe–NiR reactions
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DOI: 10.1039/d2sc06704h
Abstract: Nitrite reductase (NiR) catalyzes nitrite (NO2−) to nitric oxide (NO) transformation in the presence of an acid (H+ ions/pH) and serves as a critical step in NO biosynthesis. In addition to the NiR enzyme, NO… read more here.
Keywords: equiv; chemistry; acid induced; nir reactions ... See more keywords