Synthesis of Highly Twisted, Nonplanar Aromatic Macrocycles Enabled by Axially Chiral 4,5-Diphenylphenanthrene Building Block.
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DOI: 10.1021/jacs.9b13549
Abstract: The synthesis, structures, and properties of highly twisted, nonplanar aromatic macrocycles are described. These macrocycles with an approximately 90° twist angle were synthesized by an effective synthetic approach through a quadruple Suzuki-Miyaura coupling of 4,5-bisarylphenanthrene… read more here.
Keywords: building block; twisted nonplanar; nonplanar aromatic; highly twisted ... See more keywords