Efficient Purification of 2,6-Lutidine by Nonporous Adaptive Crystals of Pillararenes.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c11776
Abstract: 2,6-Lutidine (2,6-LT) is a very important raw material in the chemical industry, but the impurities of 3-picoline (3-PC) and 4-picoline (4-PC) existing in 2,6-LT seriously affect its quality. Considering different molecular sizes of these three… read more here.
Keywords: adaptive crystals; nonporous adaptive; efficient purification; lutidine nonporous ... See more keywords
Cis-Trans Selectivity of Haloalkene Isomers in Nonporous Adaptive Pillararene Crystals.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b06188
Abstract: The separation of haloalkene cis-trans isomers is difficult to achieve, yet highly desired in the chemical industry. Here, we report an energy-efficient adsorptive separation of 1,4-dichloro-2-butene (DCB) cis-trans isomers using nonporous adaptive crystals of perethylated… read more here.
Keywords: cis; haloalkene; nonporous adaptive; trans dcb ... See more keywords
Rim-differentiated pillar[5]arene based nonporous adaptive crystals.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc07124f
Abstract: The first rim-differentiated pillar[5]arene based nonporous adaptive crystals (NACs) were developed and used to separate dichloromethane from a halomethane mixture with 99.1% purity. read more here.
Keywords: rim differentiated; pillar arene; based nonporous; nonporous adaptive ... See more keywords