Tunable Proton Conductivity and Color in a Nonporous Coordination Polymer via Lattice Accommodation to Small Molecules.
Sign Up to like & getrecommendations! Published in 2021 at "Advanced science"
DOI: 10.1002/advs.202102619
Abstract: Nonporous coordination polymers (npCPs) able to accommodate molecules through internal lattice reorganization are uncommon materials with applications in sensing and selective gas adsorption. Proton conduction, extensively studied in the analogue metal-organic frameworks under high-humidity conditions,… read more here.
Keywords: color; coordination; tunable proton; proton conductivity ... See more keywords
Irreversible conversion of nanoporous lead(II) metal–organic framework to a nonporous coordination polymer upon thermal treatment
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DOI: 10.1016/j.poly.2018.09.009
Abstract: Abstract The reaction between 1,4-benzenedicarboxylic acid and Pb(NO3)2 in the presence of hydrogen peroxide and triethylamine with mechanochemical solid–solid and solid–gas processes results in formation of [Pb(1,4-BDC)(C2H5OH)(C2H5OH)]n (1) nanoflowers. This compound also recognized as MOF-70.… read more here.
Keywords: irreversible conversion; coordination polymer; nonporous coordination;
Crystallographic Visualization of a Guest-Induced Solar-Driven Cycloaddition Reaction Based on a Recyclable Nonporous Coordination Polymer.
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DOI: 10.1021/acs.inorgchem.1c02477
Abstract: Stimuli-responsive solids with adjustable photophysical properties are particularly attractive because they can be used as smart materials in anticounterfeiting, information storage, holographic imaging, and other fields. Herein, we report a unique nonporous coordination polymer, {[Ag(3,3'-dpe)](2,2'-Hbpdc)}n… read more here.
Keywords: h2o mecn; coordination polymer; mecn; nonporous coordination ... See more keywords
Sequential single-crystal-to-single-crystal vapochromic inclusion in a nonporous coordination polymer: unravelling dynamic rearrangement for selective pyridine sensing
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DOI: 10.1039/d1qi00059d
Abstract: Unprecedent selective and reversible pyridine solid–vapor sequential inclusion in a nonporous Fe(ii) coordination polymer accompanied by a color change is presented. Although the internal reorganization is significant, the process remains SCSC. read more here.
Keywords: inclusion nonporous; single crystal; nonporous coordination; coordination polymer ... See more keywords