Spatial Structure and Nontrivial Stereodynamics of Tricyclic Perhydro-1,2,4,5-Tetrazines
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DOI: 10.1007/s10593-019-02435-3
Abstract: Thermolysis of 6-aryl-1,5-diazabicyclo[3.1.0]hexanes in methanol leads to the respective dimers, 5,11-diaryltetrahydro-1H,7Hdipyrazolo[1,2-a:1',2'-d]tetrazines. X-ray structural analysis of these compounds reveals the perhydrotetrazine ring adopting a chair conformation with the equatorially fused five-membered rings and with the equatorial… read more here.
Keywords: spatial structure; nontrivial stereodynamics; stereodynamics tricyclic; structure nontrivial ... See more keywords