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A novel tetramer copper(I) complex containing diallylphosphine ligands: Synthesis, characterization and catalytic application in A3-coupling (Aldehyde-Amine-Alkyne) reactions

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Published in 2017 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2017.07.038

Abstract: Abstract A novel tetrameric copper(I) complex containing tert-butyldiallylphosphine ligands, [CuCl{tBu-P(CH2CH = CH2)2}]4 (2), has been synthesized and characterized by structural and spectroscopic methods. X-ray diffraction analysis showed that 2 has a cubane-like solid structure of formula [CuCl{κ1(P)-tBu-P(CH2CH = CH2)2}]4. In… read more here.

Keywords: novel tetramer; copper complex; tetramer copper; copper ... See more keywords