Articles with "noyori ikariya" as a keyword



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Hydrogen-Bonding Ability of Noyori–Ikariya Catalysts Enables Stereoselective Access to CF3-Substituted syn-1,2-Diols via Dynamic Kinetic Resolution

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Published in 2023 at "ACS Catalysis"

DOI: 10.1021/acscatal.3c00980

Abstract: Stereopure CF3-substituted syn-1,2-diols were prepared via the reductive dynamic kinetic resolution of the corresponding racemic α-hydroxyketones in HCO2H/Et3N. (Het)aryl, benzyl, vinyl, and alkyl ketones are tolerated, delivering products with ≥95% ee and ≥87:13 syn/anti. This… read more here.

Keywords: noyori ikariya; cf3 substituted; substituted syn; dynamic kinetic ... See more keywords