Sign Up to like & get
recommendations!
2
Published in 2023 at "ACS Catalysis"
DOI: 10.1021/acscatal.3c00980
Abstract: Stereopure CF3-substituted syn-1,2-diols were prepared via the reductive dynamic kinetic resolution of the corresponding racemic α-hydroxyketones in HCO2H/Et3N. (Het)aryl, benzyl, vinyl, and alkyl ketones are tolerated, delivering products with ≥95% ee and ≥87:13 syn/anti. This…
read more here.
Keywords:
noyori ikariya;
cf3 substituted;
substituted syn;
dynamic kinetic ... See more keywords