Intricate Road to Linear Anionic Nickel(I) Hexamethyldisilazanide [Ni(N(SiMe3)2)2].
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DOI: 10.1021/acs.inorgchem.2c00214
Abstract: In this report, we present intricate pathways for the synthesis of linear nickel(I) silylamide K{m}[Ni(NR2)2] (NR2 = -N(SiMe3)2). This is achieved first via the reduction of nickel(II) trisamide Li(donor)4[Ni(NR2)3] (Li(thf)x[1]) with KC8 in the presence… read more here.
Keywords: nickel; road linear; nr2; sime3 ... See more keywords