Synthesis of two new copper-sandwiched polyoxotungstates and the influence of nuclear number on catalytic hydrogen evolution activity
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DOI: 10.1039/d0nj02065f
Abstract: To focus on renewable energy, we have been devoted to developping energy-efficient, robust and low cost water reduction catalysts (WRCs). Two hybrid inorganic–organic hexa/octa-CuII-sandwiched POM: [Cu(dap)2]2[{Cu8(dap)4(H2O)2} (SiW9O34)2]·7H2O (1) and [Cu(dap)2(H2O)]2[Cu(dap)2]2[{Cu6(dap)2}(SiW9O34)2]·8H2O (2) (dap = 1,2-diaminopropane, 1,4-H2NDC… read more here.
Keywords: chemistry; new copper; dap; nuclear number ... See more keywords
Impact of nuclear number on SHG and THG performances: A comparative study of chiral mono- and dinuclear TbIII complexes with identical organic ligands
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DOI: 10.1039/d5ce00697j
Abstract: The reactions between Tb(dbm)3(H2O) and chiral bis-bidentate N-donor, (+)-2,5-bis(4ʹ,5ʹ-pinene-2ʹ-pyridyl)pyrazine (S-L), in distinct molar ratios of 1:1 and 2:1, yielded two mono- and dinuclear chiral TbIII complexes, [Tb(dbm)3(S-L)]•2H2O (S-Tb-1) and [Tb2(dbm)6(S-L)]•4H2O... read more here.
Keywords: mono dinuclear; impact nuclear; tbiii complexes; nuclear number ... See more keywords