On the Nuclearity of Completely 1-Summing Mapping Spaces
Sign Up to like & getrecommendations! Published in 2020 at "Acta Mathematica Scientia"
DOI: 10.1007/s10473-020-0623-6
Abstract: In this paper, we investigate the λ-nuclearity in the system of completely 1-summing mapping spaces (Π 1 (·, ·), π 1 ). In Section 2, we obtain that ℂ is the unique operator space that… read more here.
Keywords: completely summing; section; nuclearity completely; mapping spaces ... See more keywords
Sputtering of silicon by atomic and cluster bismuth ions: An influence of projectile nuclearity and specific kinetic energy on the sputter yield
Sign Up to like & getrecommendations! Published in 2021 at "Vacuum"
DOI: 10.1016/j.vacuum.2021.110188
Abstract: Abstract An influence of the specific kinetic energy Esp and nuclearity n of Bin+ (n = 1–4) projectiles on the sputter yield of Si was studied by means of the volume loss method. It was found that… read more here.
Keywords: kinetic energy; energy; nuclearity; specific kinetic ... See more keywords
Organic-Inorganic High-Valence Sn18-oxo Clusters: Direct Utilization of an Inorganic Sn(IV) Source to Improve the Nuclearity and Electrocatalytic CO2 Reduction Properties.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00038
Abstract: The high-valence tin-oxo clusters are of great significance because of their structural diversity and potential applications in many fields, e.g., catalysis, extreme ultraviolet (EUV) lithography, and so on. The synthesis of high-nuclearity tin-oxo clusters remains… read more here.
Keywords: oxo clusters; sn18 oxo; tin; oxo ... See more keywords
Synthesis, Structure, and Magnetic Properties of an Fe36 Dimethylarsinate Cluster: The Largest "Ferric Wheel".
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02841
Abstract: The synthesis and characterization of a high-nuclearity FeIII/O/arsinate cluster is reported within the salt [Fe36O12(OH)6(O2AsMe2)63(O2CH)3(H2O)6](NO3)12 (1). The compound was prepared from the reaction of Fe(NO3)3·9H2O, dimethylarsinic acid (Me2AsO2H), and triethylamine in a 1:2:4 molar ratio… read more here.
Keywords: nuclearity; synthesis; wheel; cluster ... See more keywords
Bismuth-Polyoxocation Coordination Networks: Controlling Nuclearity and Dimension-Dependent Photocatalysis.
Sign Up to like & getrecommendations! Published in 2023 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.3c01172
Abstract: Bismuth-oxocluster nodes for metal-organic frameworks (MOFs) and coordination networks/polymers are less prolific than other families featuring zinc, zirconium, titanium, lanthanides, etc. However, Bi3+ is non-toxic, it readily forms polyoxocations, and its oxides are exploited in… read more here.
Keywords: nuclearity; coordination; photocatalysis; ray ... See more keywords
Assemblies of Increasingly Large Ln-Containing Polyoxoniobates and Intermolecular Aggregation-Disaggregation Interconversions.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c09546
Abstract: An oxalate-assisted lanthanide (Ln) incorporation strategy is first demonstrated for creating rare high-nuclearity Ln-containing polyoxoniobates (PONbs). With the strategy, a series of high-nuclearity Ln-containing PONbs of 50-nuclearity Dy2Nb48, 103-nuclearity Dy7Nb96, 200-nuclearity Dy10Nb190, and 206-nuclearity Dy14Nb192… read more here.
Keywords: nuclearity; containing polyoxoniobates; aggregation disaggregation; dy10nb190 ... See more keywords
Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01019b
Abstract: The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]2 in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and… read more here.
Keywords: sphos; geometry; spectroscopy; catalytic activity ... See more keywords
Ligand-based control of nuclearity in (NHC)gold(I) sulfides.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt02616j
Abstract: N-Heterocyclic carbene (NHC) ligands support gold(I) sulfide complexes of varying nuclearity and charge. For sterically undemanding ligands, gold(I) chlorides react with sulfide to form trigold μ3-sulfido cations as the first observed products. The ligand IMes… read more here.
Keywords: ligand based; cation; control nuclearity; ylidene ... See more keywords
Composition-driven archetype dynamics in polyoxovanadates
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc01004f
Abstract: Molecular metal oxides often adopt common structural frameworks (i.e. archetypes), many of them boasting impressive structural robustness and stability. However, the ability to adapt and to undergo transformations between different structural archetypes is a desirable… read more here.
Keywords: nuclearity; archetype dynamics; chemistry; dynamics polyoxovanadates ... See more keywords
Framing Nuclearity: Online Media Discourses in Lithuania
Sign Up to like & getrecommendations! Published in 2021 at "Media and Communication"
DOI: 10.17645/mac.v9i2.3818
Abstract: This article refers to the concept of nuclearity as a broader technopolitical phenomenon that implies a political and cultural configuration of technical and scientific matters. The nuclear media discourses become a site of tensions, struggles,… read more here.
Keywords: media coverage; nuclear issues; power; nuclearity ... See more keywords