84-Nuclearity Lanthanide-Aluminum Cyclic Clusters: Promising Materials for Iodine Capture and Storage.
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DOI: 10.1021/jacs.5c00684
Abstract: Developing high-performance adsorbents for iodine uptake and storage has become an urgent priority for safe disposal and long-term storage of nuclear waste. In this work, two cyclic lanthanide-aluminum clusters with the formula [Ln12Al72(hmp)60(C2H5O2)6(μ2-OH)120(μ3-OH)18(H2O)30]Cl24·(NO3)24·(H2O)x (Ln =… read more here.
Keywords: cyclic clusters; nuclearity lanthanide; iodine adsorption; storage ... See more keywords