Formation and Structures of the μ4-Oxygen-Bridged High-Nuclearity Lead(II) Clusters from a Lead Propane-2-thiolate Complex
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DOI: 10.1007/s10876-020-01917-1
Abstract: Interaction of [Pb(SiPr)2]n with 1.5 equiv. of AgNO3 in DMF under aerobic conditions at room temperature gave a cationic lead-centered thiolate cluster [Pb13(SiPr)6O8](NO3)4 (1). While treatment of [Pb(SiPr)2]n in refluxing DMF in air afforded a… read more here.
Keywords: lead clusters; oxygen bridged; high nuclearity; nuclearity lead ... See more keywords