Thermochromism and piezochromism of an atomically precise high-nuclearity silver sulfide nanocluster.
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DOI: 10.1039/d0cc07085h
Abstract: A novel high-nuclearity silver sulfide nanocluster [Ag50S7(SC6H4F)36(dppp)6]·4DMI, (hereafter abbreviated as 1⋅4DMI) was synthesised. Solvent-free crystals of 1 displayed a completely reversible narrowing and broadening of the optical band gap that was accompanied by visual thermochromism… read more here.
Keywords: high nuclearity; nuclearity silver; silver sulfide; sulfide nanocluster ... See more keywords
Generation of High Nuclearity Silver(I) and Gold(I) Species Using Simple N-Heterocyclic Carbene Complexes
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DOI: 10.1039/d4nj05260a
Abstract: 1,3-Bis(2,6-isopropylphenyl)-imidazol-2-ylidene-silver(I) chloride [Ag(IPr)Cl], when combined with the appropriate reactants, solvents, and reaction sequence, can serve as a straightforward synthon for the generation of silver nanoclusters stabilized by dichalcogenophosphate ligands. Fundamental... read more here.
Keywords: high nuclearity; gold species; generation; nuclearity silver ... See more keywords