Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.04.062
Abstract: Abstract The ligand-redistribution reactions of aryl- and alkoxy-hydrosilanes can potentially cause the formation of gaseous hydrosilanes, which are flammable and pyrophoric. The ability of generic nucleophiles to initiate the ligand-redistribution reaction of commonly used hydrosilane… read more here.
Keywords: induced ligand; reactions alkoxy; ligand rearrangement; ligand redistribution ... See more keywords
Sensitive Assays by Nucleophile-Induced Rearrangement of Photoactivated Diarylethenes.
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DOI: 10.1021/jacs.8b02982
Abstract: Upon light-induced isomerization, diarylethenes (DAEs) equipped with reactive aldehyde moieties rearrange selectively in the presence of amines, accompanied by decoloration. In a comprehensive study, the probe structure was optimized with regard to its inherent reactivity… read more here.
Keywords: photoactivated diarylethenes; assays nucleophile; sensitive assays; rearrangement photoactivated ... See more keywords
Nucleophile-induced ring contraction in pyrrolo[2,1-c][1,4]benzothiazines: access to pyrrolo[2,1-b][1,3]benzothiazoles
Sign Up to like & getrecommendations! Published in 2023 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.19.46
Abstract: Pyrrolo[2,1-b][1,3]benzothiazoles are an important class of fused sulfur and nitrogen-containing heterocycles intensively studied in medicinal chemistry and pharmacology. In the present paper, a new synthetic approach to pyrrolobenzothiazoles is developed based on 1,4-thiazine ring contraction… read more here.
Keywords: pyrrolo; nucleophile induced; chemistry; pyrrolo benzothiazoles ... See more keywords