Articles with "nucleophiles released" as a keyword



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Synthesis of Benzhydryl-Substituted Amines by Silanolate-Mediated Aldimine Arylation with Functionalized Aryl Nucleophiles Released from Diazene-Based Reagents.

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Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c03798

Abstract: A transition-metal-free protocol for the arylation of N-phenyl- and N-benzoyl-substituted, benzaldehyde-derived imine derivatives with functionalized aryl pronucleophiles is reported. The aryl nucleophiles are released from silicon-protected aryl-substituted diazenes by desilylation with potassium trimethylsilanolate concomitant with… read more here.

Keywords: synthesis benzhydryl; functionalized aryl; aryl nucleophiles; benzhydryl substituted ... See more keywords