Catalytic nucleophilic 'umpoled' π-allyl reagents.
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DOI: 10.1039/c7cs00449d
Abstract: After seminal Tsuji-Trost reactions (palladium catalyzed allylation of nucleophiles via π-allyl intermediates as electrophiles), the idea of reversal reactivity of π-allyl intermediates (i.e. π-allyl as nucleophiles) has been stated since the eighties. Thanks to different… read more here.
Keywords: catalytic nucleophilic; allyl intermediates; nucleophilic umpoled; allyl ... See more keywords