Sulphido bridged dinuclear quadruple bond cleavage product from the reaction between Re2(µ-O2CCH3)4Cl2 and dithiocarbamate: An experimental and theoretical study
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DOI: 10.1016/j.poly.2021.115422
Abstract: Abstract Sodium salts of dimethyldithiocarbamate, diethyldithiocarbamate and pyrrolidinedithiocarbamate react with the quadruply bonded dirhenium(III,III) complex [Re2(μ-O2CCH3)4Cl2] (1) in ethanol to afford the sulphido bridged dinuclear quadruple-bond cleavage products of the type [Re2(μ-S)(LR)4(OH2)2] (2(LR)) where LR… read more here.
Keywords: o2cch3 4cl2; sulphido bridged; bridged dinuclear; re2 o2cch3 ... See more keywords