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Published in 2017 at "Organic chemistry frontiers"
DOI: 10.1039/c7qo00062f
Abstract: The highly efficient asymmetric syntheses of a pair of enantiomers, (S)-(−)-trolline and (R)-(+)-oleracein E, from commercially available 2-methyl-3-butyn-2-ol, benzaldehyde and 6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline have been achieved in five steps with the catalytic enantioselective C1-alkynylation of 6,7-dimethoxy-3,4-dihydroisoquinoline as…
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Keywords:
trolline oleracein;
isoquinoline alkaloids;
naturally occurring;
occurring isoquinoline ... See more keywords