Articles with "octahedral clusters" as a keyword



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Research of the spin-Hamiltonian parameters and tetragonal distortion for Dy3+ octahedral clusters in the tetragonal phase of Rb2NaYF6

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Published in 2017 at "Polyhedron"

DOI: 10.1016/j.poly.2017.03.016

Abstract: Abstract The spin-Hamiltonian parameters ( g factors g i and hyperfine structure constants A i 161 , A i 163 , where i  = || or ⊥) for 161 Dy 3+ and 163 Dy 3+ isotopes… read more here.

Keywords: hamiltonian parameters; tetragonal distortion; octahedral clusters; spin hamiltonian ... See more keywords
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Cubic Fd3¯c Ba8{Ni,Mn}4[BP3O11(OH)2]4 with anionic units of four-octahedral clusters and four borophosphate groups embedded into Ba-cations medium

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Published in 2019 at "Solid State Sciences"

DOI: 10.1016/j.solidstatesciences.2019.106013

Abstract: Abstract Single crystals of new high symmetrical borophosphate, Ba8{Ni2+0.7Mn2+0.2Fe3+0.014⎕0.086}4⋅[BP3O10.9(OH)2.1]4, sp.gr. Fd 3 ¯ c, a = 25.36 A, are synthesized in multi-component hydrothermal systems. It is large inorganic structure with the anionic part, characterized as a complex unit… read more here.

Keywords: octahedral clusters; borophosphate; borophosphate groups; ba8 ... See more keywords
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Local structure origin of ultrafast crystallization driven by high-fidelity octahedral clusters in amorphous Sc0.2Sb2Te3

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Published in 2019 at "Applied Physics Letters"

DOI: 10.1063/1.5085502

Abstract: Phase-change material Sc0.2Sb2Te3 (SST) can remarkably boost the writing speed of memory devices due to the extremely fast crystallization. It was demonstrated that the fast crystallization is because Sc stabilizes the 4-fold rings which act… read more here.

Keywords: phase; octahedral clusters; liquid amorphous; crystallization ... See more keywords