Using N-Heterocyclic Carbenes as Weak Equatorial Ligands to Design Single-Molecule Magnets: Zero-Field Slow Relaxation in Two Octahedral Dysprosium(III) Complexes.
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DOI: 10.1021/acs.inorgchem.1c03429
Abstract: We report the synthesis, structures, and magnetic investigations of two new octahedral dysprosium complexes, based on the original N-heterocyclic carbene (NHC) tridentate bis(phenoxide) ligand, of the respective formulas mer-[DyL(THF)2Cl] (1) and mer-[DyL(THF)3][BPh4] (2), where L… read more here.
Keywords: single molecule; molecule magnets; octahedral dysprosium; slow relaxation ... See more keywords