Expanding the Toolbox of Octahedral Molybdenum Clusters and Nanocomposites Made Thereof: Evidence of Two-Photon Absorption Induced NIR Emission and Singlet Oxygen Production.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00517
Abstract: Bright NIR phosphorescence from octahedral molybdenum clusters has been known since the 1980s. However, their behavior toward NIR excitation has never been investigated. Here we report their abilities to emit NIR light and produce singlet… read more here.
Keywords: two photon; octahedral molybdenum; singlet oxygen; photon absorption ... See more keywords
Phosphinate Apical Ligands: A Route to a Water-Stable Octahedral Molybdenum Cluster Complex.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02569
Abstract: Recent studies have unraveled the potential of octahedral molybdenum cluster complexes (Mo6) as relevant red phosphors and photosensitizers of singlet oxygen, O2(1Δg), for photobiological applications. However, these complexes tend to hydrolyze in an aqueous environment,… read more here.
Keywords: apical ligands; molybdenum cluster; phosphinate apical; octahedral molybdenum ... See more keywords
Octahedral Molybdenum Iodide Clusters Supported on Graphene for Resistive and Optical Gas Sensing
Sign Up to like & getrecommendations! Published in 2022 at "ACS Applied Materials & Interfaces"
DOI: 10.1021/acsami.2c15716
Abstract: This paper reports for the first time a gas-sensitive nanohybrid based on octahedral molybdenum iodide clusters supported on graphene flakes (Mo6@Graphene). The possibility of integrating this material into two different transducing schemes for gas sensing… read more here.
Keywords: gas sensing; gas; clusters supported; molybdenum iodide ... See more keywords
Octahedral Molybdenum Cluster-Based Nanomaterials for Potential Photodynamic Therapy
Sign Up to like & getrecommendations! Published in 2022 at "Nanomaterials"
DOI: 10.3390/nano12193350
Abstract: Photo/radiosensitizers, such as octahedral molybdenum clusters (Mo6), have been intensively studied for photodynamic applications to treat various diseases. However, their delivery to the desired target can be hampered by its limited solubility, low stability in… read more here.
Keywords: polymer cluster; molybdenum; octahedral molybdenum; cluster ... See more keywords