β‐Octabromo‐ and β‐Octakis(trifluoromethyl)isocorroles: New Sterically Constrained Macrocyclic Ligands
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DOI: 10.1002/open.201700035
Abstract: Abstract Presented herein is a study of the acid‐induced demetalation of two sterically hindered copper corroles, Cu β‐octabromo‐meso‐triphenylcorrole (Cu[Br8TPC]) and β‐octakis(trifluoromethyl)‐meso‐tris(p‐methoxyphenyl)corrole (Cu[(CF3)8TpOMePC]). Unlike reductive demetalation, which affords the free‐base β‐octabromocorrole, demetalation of Cu[Br8TPC] under non‐… read more here.
Keywords: octakis trifluoromethyl; cf3 8tpomepc; demetalation; free base ... See more keywords